Read more about how to correctly acknowledge RSC content.Hauptgruppenelemente, Silizium, Gruppe 14, Übergangsmetalle, Lanthanide, Seltenerdelemente, Niedervalente Verbindungen, Reaktivität, Synthese, Aromatizität, Tetrasilacyclobutadien-Dikation, Mechanismus, Chiralität, Silylen, Erdalkalimetalle, Zink, Cadmium, Phosphor, Calcium, Strontium, Barium, Yttrium, Lanthan, Cer, Samarium, Europium, Ytterbium, Silen, Polyphosphide, Metallole, Silole, Germole, Plumbole, Heterocyclen, Sandwichverbindungen, Koordinationschemie, Magnetismus, Tieftemperaturmatrix, Lewis-Base, Lewis-Säure, mesomere Stabilisierung, heterozyklische Silylene, schwere Cp-Metallole, Diastereoselektivität, terminale Olefine, Liganden Permission is not required) please go to the Copyright If you want to reproduce the wholeĪrticle in a third-party commercial publication (excluding your thesis/dissertation for which If you are the author of this article, you do not need to request permission to reproduce figuresĪnd diagrams provided correct acknowledgement is given. Provided correct acknowledgement is given. If you are an author contributing to an RSC publication, you do not need to request permission Please go to the Copyright Clearance Center request page. To request permission to reproduce material from this article in a commercial publication, Provided that the correct acknowledgement is given and it is not used for commercial purposes. This article in other publications, without requesting further permission from the RSC, Parac-Vogt,Ĭreative Commons Attribution-NonCommercial 3.0 Unported Licence. Reactivity of metal–oxo clusters towards biomolecules: from discrete polyoxometalates to metal–organic frameworksĭ. Therefore, this review aims to provide a comprehensive and critical analysis of the state of the art on biomolecular transformations promoted by metal–oxo clusters and their applications, with a particular focus on structure–activity relationships. The properties of the catalyst can also be improved through incorporation into solid supports or by linking metal–oxo clusters together to form Metal–Organic Frameworks (MOFs), which have been demonstrated to be powerful heterogeneous catalysts. Additionally, the structural versatility of metal–oxo clusters allows for the efficiency and selectivity of the biomolecular reactions they promote to be readily tuned, thereby providing a pathway towards reaction optimization. Furthermore, their reactivity towards biomolecules has also attracted interest in the development of inorganic drugs and bioanalytical tools. For instance, metal–oxo clusters and related materials have been shown to be effective catalysts for biomass conversion into renewable fuels and platform chemicals. This reactivity can be leveraged to address some of the most pressing challenges we face today, from fighting various diseases, such as cancer and viral infections, to the development of sustainable and environmentally friendly energy sources. These nanoclusters of transition metals with oxygen-based ligands have also shown promising reactivity towards several classes of biomolecules, including proteins, nucleic acids, nucleotides, sugars, and lipids. Metal–oxo clusters hold great potential in several fields such as catalysis, materials science, energy storage, medicine, and biotechnology.
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